Answer:
a) At x=14 the slope will be given by:
.
b) Then, the angle between the line and the pole will be:

where
is the angle between the tangent to the catenary and the x-axis.
Step-by-step explanation:
The catenary has the following general form:

a) The slope at any point will be given by the derivative of y.

At x=14:
.
b) The angle between the tangent to the catenary and the x-axis at a given point will be given by:
⇒

Then, the angle between the line and the pole will be:
.