Answer:
The overall standard deviation, s = 6.46 %
Given:
Sampling variance,
Analytical variance,
![s_(a) = \pm 2.4% = 0.024](https://img.qammunity.org/2020/formulas/chemistry/college/lp68jmf3o1ynzxpy1gzs59hhc2dg8lhp55.png)
Solution:
Variance additive is given by:
(1)
where
s = overall variance
Also, we know that:
Standard Deviation,
![\sigma = √(variance)](https://img.qammunity.org/2020/formulas/chemistry/college/y98cfgdqmd9dg4sgk13b1hkfsic9c26l0z.png)
Therefore the standard deviation of the sampling, analytical and overall sampling is given by taking the square root of eqn (1) on both the sides:
![s = \sqrt{s_(a)^(2) + s_(b)^(2)}](https://img.qammunity.org/2020/formulas/chemistry/college/dqhlbyl85ra95wbtear43f70l0lbkna4l9.png)
![s = \sqrt{0.024^(2) + 0.06^(2)} = 0.0646](https://img.qammunity.org/2020/formulas/chemistry/college/ayuyp8xp746uc6hp9v14df6aqm8of390o4.png)
s = 6.46 %