Methanol is a polar protic solvent among the given options.
A polar protic solvent is a solvent that has a hydrogen atom attached to an electronegative atom and is capable of donating a hydrogen bond.
Based on this definition, the polar protic solvent among the options given is methanol (CH3OH).
Methanol has a hydrogen atom attached to an oxygen atom, which makes it capable of donating a hydrogen bond.
Chloroform, acetone, acetonitrile, and diethyl ether are polar aprotic solvents, meaning they lack an acidic hydrogen atom and cannot donate a hydrogen bond.