Answer:
0.8342 grams of ethylene glycol must be added to one liter of water.
Step-by-step explanation:
Volume of water or solvent = 1 L
Density of water = 1 g/L
Mass of the water = Density × Volume = 1 g/L × 1 L = 1 g
1 g = 0.001 kg
Molal freezing constant of water = 1.86 °C/m =1.86 °C/(mol/kg)
The van't Hoff factor contribution by ethylene glycol is 1 .
i = 1
![\Delta T_f=25^oC](https://img.qammunity.org/2020/formulas/chemistry/college/5fem2kiukxl6mmj7k5uo3fy5o6yot106ek.png)
![\Delta T_f=i* K_f* m](https://img.qammunity.org/2020/formulas/chemistry/high-school/p2xvomdi0zqiixdn40zzud1i25vrkz1it8.png)
![Molality=m(mol/kg)=\frac{\text{Moles of solute}}{\text{mass of solvent in kg}}](https://img.qammunity.org/2020/formulas/chemistry/college/v6g3sintyiikhaf96vhifwhpmhei56z52v.png)
![25^oC=1* 1.86 ^oC/(mol/kg)* (Moles)/(0.001 kg)](https://img.qammunity.org/2020/formulas/chemistry/college/7rpfns0a9xzpcirz4bupnnypvxx46g09mq.png)
Moles of solute (ethylene glycol) = 0.013440860 moles
Mass of 0.013440860 moles of ethylene glycol:
![0.013440860 mol* 62.07 g/mol=0.8342 g](https://img.qammunity.org/2020/formulas/chemistry/college/nvp16s5wgi8umu17kkk2zm03s35u33uoyx.png)
0.8342 grams of ethylene glycol must be added to one liter of water.