Answer:
The answer is: CH₄ < CH₃OH < CH₃CH₂OH < HOCH₂CH₂OH
Step-by-step explanation:
Boiling point refers to the temperature at which the pressure exerted by the surrounding on the liquid is equal to the vapor pressure of the liquid. The boiling point increases as the molar mass of the substance increases.
Since the molar mass increases in the order:
CH₄ < CH₃OH < CH₃CH₂OH < HOCH₂CH₂OH
Therefore, the order of increasing boiling point:
CH₄ < CH₃OH < CH₃CH₂OH < HOCH₂CH₂OH