Final answer:
In (a), the theoretical yield of ethanol when starting with 68.0 g of glucose is 34.7 g. In (b), the percent yield of this reaction when 13.0 g of ethanol is produced is 37.5%.
Step-by-step explanation:
(a) To find the theoretical yield of ethanol, we need to calculate the moles of glucose and then use the stoichiometry of the reaction. The molar mass of glucose is 180.16 g/mol. So, we have:
Moles of glucose = mass / molar mass = 68.0 g / 180.16 g/mol = 0.377 mol
From the balanced equation, we can see that 1 mol of glucose produces 2 mol of ethanol. Therefore, the theoretical yield of ethanol is:
0.377 mol glucose × (2 mol ethanol / 1 mol glucose) = 0.754 mol ethanol
Now, to find the mass of ethanol, we can use the molar mass of ethanol which is 46.07 g/mol:
Mass of ethanol = moles of ethanol × molar mass of ethanol = 0.754 mol × 46.07 g/mol = 34.7 g ethanol
(b) To find the percent yield, we divide the actual yield by the theoretical yield and multiply by 100:
Percent yield = (actual yield / theoretical yield) × 100 = (13.0 g / 34.7 g) × 100 = 37.5%