Answer:
Sodium iodide NaI
Magnesium chloride MgCl₂
Step-by-step explanation:
Silicon dioxide SiO₂ it is not soluble in water, so it can not be recrystallized from water, it is a white solid and the boiling point is 2230 °C. This one is not the unknown solid.
Sodium iodide NaI it is soluble in water, it has a white color and the boiling point is 1304 °C . This can be the unknown solid.
Magnesium chloride MgCl₂ is soluble in water, it have a white color and the boiling point is 1,412 °C . This can be the unknown solid.
Phosphorus tribromide PBr₃ is will start a hydrolysis reaction in water, it is a colorless liquid and it has a boiling point of 173 °C. This one is not the unknown solid.