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The gauge pressure in your car tires is 2.70 ✕ 105 N/m2 at a temperature of 35.0°C when you drive it onto a ship in Los Angeles to be sent to Alaska. What is their gauge pressure (in atm) later, when their temperature has dropped to −42.0°C? Assume the tires have not gained or lost any air.

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Answer:

The final gauge pressure will be 1.74 atm

Step-by-step explanation:

Assume air tire as an ideal gas, therefore, it is considered:

  • incompressible gas: the gas density will be constant.
  • there is no change in the amount of matter: the number of moles is constant (because there is no gain or loss of air during the process)

The expression to describe the ideal gas process is:


P.v=Rg.T

Where v is the specific volume or the inverse of the density p:


P/p=Rg.T (2)

Then the P and T are the absolute pressure and temperature respectively. Rg represents the particular gas constant for air, Rg is equal to 287 J/kg-K. Take into account that P and T must be expressed in Pascal and Kelvin respectively.

By reorganizing the expression (2) as below is doing:


P/T=Rg.p

Can be noticed that the product Rg*p is constant therefore relation P/T will also be constant. For two different states 1 and 2 of the ideal gas, it follows:


P_(1)/T_(1)=P_(2)/T_(2) (3)

Here, states 1 and 2 will represent the state before and after arriving in Alaska.

Note that the temperatures given are in °C so it must be converted:


T(K)=273+T(°C)


T_(1) (K)=273+35


T_(1)=308 K


T_(2) (K)=273-42


T_(2)=231 K

Note also that the pressure given is the gauge pressure therefore it must be expressed as absolute pressure:


Pa (Pa)=Patm(Pa)+Pg(Pa)

Where Patm is the atmosphere pressure and is equal to 101325 Pa then for Pg of 2.7 10^5 Pa:


Pa_(1) (Pa)= 101325 Pa+ 270000 Pa


Pa_(1) (Pa)= 371325 Pa

Solving equation (3) for pressure at state 2:


P_(2)=P_(1)*T_(2)/T_(1)

For the temperatures and pressure calculated values:


P_(2)= 371325 Pa * \frac231K}/{308K}


P_(2)= 278493.75 Pa

As is required the gauge pressure and not the absolute pressure:


Pg (Pa)=Pa(Pa)-Patm(Pa)


Pg_(2) (Pa)= 278493.75 -101325(Pa)


Pg_(2) (Pa)= 177168 Pa

Finally re expressing the pressure in atm units:


P (atm)=P (Pa)*(1 atm)/(101325 Pa)


P_(2) (atm)=177168*(1 atm)/(101325 Pa)


P_(2) (atm)=1.74 atm

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