Answer :
(a) The value of
of the lactate ion is,
![7.14* 10^(-39)](https://img.qammunity.org/2020/formulas/chemistry/college/oqh49nmnf1req3bcav2jfjci7fuhx4tknd.png)
(b) The value of
of the conjugate base of pyruvic acid is,
![3.53* 10^(-38)](https://img.qammunity.org/2020/formulas/chemistry/college/16x6n669h3ij5k3jvxwvm1tqjpvo6vghhq.png)
Explanation :
Solution for (a) :
As we are given :
![K_a=1.4* 10^(24)](https://img.qammunity.org/2020/formulas/chemistry/college/p53nc25jwa8vl63uv0mt5jcnog4as1oe0x.png)
As we know that,
![K_a* K_b=K_w](https://img.qammunity.org/2020/formulas/chemistry/high-school/lkbpmfccnf4b8ase1q6m6p3eqz89hnqkcm.png)
where,
= dissociation constant of an acid =
![1.4* 10^(24)](https://img.qammunity.org/2020/formulas/chemistry/college/ruhn48r7otfvcyeyuzl1ltflxt8yu4706i.png)
= dissociation constant of a base = ?
= dissociation constant of water =
![1* 10^(-14)](https://img.qammunity.org/2020/formulas/chemistry/college/udgt60kdxatzr05w2mt69h6rltremv0z3y.png)
Now put all the given values in the above expression, we get the dissociation constant of a base (lactate ion).
![1.4* 10^(24)* K_b=1* 10^(-14)](https://img.qammunity.org/2020/formulas/chemistry/college/kco08jn17yxofw7lbf19wqhcf4fcakut8f.png)
![K_b=7.14* 10^(-39)](https://img.qammunity.org/2020/formulas/chemistry/college/gwlm3336ilsmhj00r47qmr1bynhi2kdmsb.png)
Therefore, the value of
of the lactate ion is,
![7.14* 10^(-39)](https://img.qammunity.org/2020/formulas/chemistry/college/oqh49nmnf1req3bcav2jfjci7fuhx4tknd.png)
Solution for (b) :
As we are given :
![K_a=2.83* 10^(23)](https://img.qammunity.org/2020/formulas/chemistry/college/typwjn6t578deaxup7kab0at3loo3gl4kq.png)
As we know that,
![K_a* K_b=K_w](https://img.qammunity.org/2020/formulas/chemistry/high-school/lkbpmfccnf4b8ase1q6m6p3eqz89hnqkcm.png)
where,
= dissociation constant of an acid =
![2.83* 10^(23)](https://img.qammunity.org/2020/formulas/chemistry/college/2wcjldsti3sapdpue8wlp15jxv3cqtuitk.png)
= dissociation constant of a base = ?
= dissociation constant of water =
![1* 10^(-14)](https://img.qammunity.org/2020/formulas/chemistry/college/udgt60kdxatzr05w2mt69h6rltremv0z3y.png)
Now put all the given values in the above expression, we get the dissociation constant of a base (conjugate base of pyruvic acid).
![2.83* 10^(23)* K_b=1* 10^(-14)](https://img.qammunity.org/2020/formulas/chemistry/college/kfedcztxbabkm8ggeq7jwm91m56h7xd79d.png)
![K_b=3.53* 10^(-38)](https://img.qammunity.org/2020/formulas/chemistry/college/c0befbk4h9yt8bwx7byz6joo9avvvn1tqs.png)
Therefore, the value of
of the conjugate base of pyruvic acid is,
![3.53* 10^(-38)](https://img.qammunity.org/2020/formulas/chemistry/college/16x6n669h3ij5k3jvxwvm1tqjpvo6vghhq.png)