Step-by-step explanation:
When small amount of solute is added to a solvent and if it readily dissolves then this type of solution is known as an unsaturated solution.
For example, in the given situation when calcium chloride is first dissolved in water then it completely dissolves and this makes the solution unsaturated.
And, a saturated solution is defined as a solution which contains maximum amount of solute.
So, when a spatula tip full of calcium chloride is added into water then it is unable to dissolve the solute. This means the solution has become saturated.
Thus, we can conclude that solution before adding the spatula tip amount is unsaturated and after adding the spatula tip amount the solution becomes saturated.