Answer: The mass of NaF that must be mixed with 25 mL of water is 0.91 grams
Step-by-step explanation:
We are given:
Volume of water = 25 mL
To calculate the mass of water, we use equation used to calculate density:

Density of water = 1 g/mL
Volume of water = 25 mL
Putting values in above equation, we get:

We are given:
3.5 % (m/m) NaF solution
This means that 3.5 grams of NaF is present in 100 g of solution
Mass of water in solution = 100 - 3.5 = 96.5 g
To calculate the mass of NaF mixed with 25 mL of water, we use unitary method:
In 96.5 grams of water, the mass of NaF added is 3.5 grams
So, in 25 grams of water, the mass of NaF that must be added will be =

Hence, the mass of NaF that must be mixed with 25 mL of water is 0.91 grams