Answer:
46.13 g/mol.
Step-by-step explanation:
∵ ΔTf = Kf.m.
Where, ΔTf is the depression in the freezing point of water = 5.0°C.
Kf is the the molal freezing point depression constant of water = 1.86 °C/m.
m is the molality of the solution (moles of solute per kilogram of solvent.)
∵ ΔTf = Kf.m.
∴ m = ΔTf /Kf = (5.0°C)/(1.86 °C/m) = 2.688 m.
∵ m = no. of moles of solute / kg of solvent.
∴ 2.688 m = (mass of solute / molar mass of solute) / kg of water.
∴ Molar mass of solute = (mass of solute)/(2.688)(kg of water) = (12.4 g)/(2.688)(0.10 kg) = 46.13 g/mol.