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Is O2 always a double bond?

In the question about Bond Enthalpy it is 2H2O2 → 2H2O + O2

In the answers O-O is a double bond. How do I find out if something has a double bond without looking at the answers?

User Drsndodiya
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2 Answers

6 votes

BRINCLHOF

Br

I

N

Cl

H

O

F

all have dounle bonds.

You could also do lewis structures for each molecule to figure out the structure.

User Rowana
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5.7k points
3 votes
  • O-O single bonds and H-O single bonds in
    \text{H}_2\text{O}_2 molecules.
  • H-O single bonds in
    \text{H}_2\text{O} molecules.
  • O=O double bonds in
    \text{O}_2 molecules.

Step-by-step explanation

How many valence electrons do atoms in each molecule need for them to be stable?

  • Each H atom needs two valence electrons to be stable.
  • Each atom of an element other than H needs eight valence electron to be stable.
  • There are two H atoms and two O atoms in an
    \text{H}_2\text{O}_2 molecule. Atoms in each
    \text{H}_2\text{O}_2 need
    2 * 1 + 2* 2 = 6 more electrons to be stable.
  • There are two H atoms and one O atom in an
    \text{H}_2\text{O} molecule. Atoms in each
    \text{H}_2\text{O} molecule need
    2 * 1 + 2= 4 more electrons to be stable.
  • There are two O atoms in an
    \text{O}_2 molecule. Atoms in each
    \text{O}_2 molecule need
    2 * 2 = 4 more electrons to be stable.

How many chemical bonds in each molecule?

Each chemical bond adds one valence electron to each bonding atom. Each chemical bond connects two atoms. As a result, each chemical bond adds two valence electrons to the molecule.

  • Each
    \text{H}_2\text{O}_2 molecule needs
    6 / 2 = 3 chemical bonds.
  • Each
    \text{H}_2\text{O} molecule needs
    4 / 2 = 2 chemical bonds.
  • Each
    \text{O}_2 molecule needs
    4 /2= 2 chemical bonds.

What chemical bonds are these? Again, each H atom needs only one more valence electron to be stable. It will share only one electron with O and form one H-O bond. The rest of the chemical bonds are between O atoms.

  • There are two H atoms in each
    \text{H}_2\text{O}_2 molecule, which form two H-O bonds. Two of the three chemical bonds in this molecule are H-O. The other is an O-O single bond between the two O atoms.
  • There are two H atoms in each
    \text{H}_2\text{O} molecule, which form two H-O bonds. Both chemical bonds in this molecule are H-O. There's no O-O bond in this molecule.
  • There is no H atom in
    \text{O}_2 molecules. Both chemical bonds are between O atoms. However, there are only two O atoms. There must be two chemical bonds between the two O atoms. That bond will be an O-O double bond.
User Ilya Dmitriev
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