Answer: π
Explanation:
By definition, irrational numbers are those numbers that cannot be written as a fraction.
Keeping this on mind, you have that:
1/3 is a fraction, then it is not irrational.
2/3 is a fraction, then it is not irrational.
3.624 can be written as 453/125 (it is a fraction, then it is not irrational).
π cannot be writte as a fraction. It is irrational.
0.87 can be written as 87/100 (it is a fraction, then it is not irrational).
-5 can be written as -5/1 then it is not irrational.