Answer:
290.0 L.
Step-by-step explanation:
- From the balanced equation: C + 2H₂ → CH₄,
it is clear that 1.0 mole of C reacts with 2.0 moles of H₂ to produce 1.0 mole of CH₄.
- We should convert the liters of CH₄ (145.0 L) to moles using the relation:
PV = nRT,
where, P is the pressure of the CH₄ gas produced in atm (P = 1.0 atm at STP).
V is the volume of the CH₄ gas produced in L (V = 145.0 L).
n is the no. of moles of the CH₄ gas produced in mol.
R is the general gas constant (R = 0.082 L.atm/mol.K).
T is the temperature of the CH₄ gas produced in K (T = 273.15 K at STP).
∴ n = PV/RT = (1.0 atm)(145.0 L)/(0.082 L.atm/mol.K)(273.15 K) = 6.47 mol.
Using cross multiplication:
2.0 moles of H₂ produce → 1.0 mole of CH₄, from the stichiometry.
??? mole of H₂ produce → 6.47 mole of CH₄.
∴ The no. of moles of H₂ consumed to produce 145.0 L CH₄ = (2.0)(6.47)/(1.0) = 12.94 mol.
Now, we can get the liters of H₂ consumed to produce 145.0 L CH₄:
∴ V = nRT/P = (12.94 mol)(0.082 L.atm/mol.K)(273.15 K)/(1.0 atm) = 290.0 L.