D synthesis reaction
Single replacement will be like
Cl2 + 2NaBr —> 2NaCl + Br2
This is because only one element is moved from the reactants to the products (Cl)
Combustion will be like
CH4 + 2O2 —> 2H2O + CO2
Which involves oxygen gas
Decomposition is
NaCl —> Na + Cl
Where the compound breaks apart
And synthesis is
Na + Cl—> NaCl
Where a compound is made
Much like your problem
Al + O2 —> Al2O3 (aluminum oxide)