Answer: Option (d) is the correct answer.
Step-by-step explanation:
A physical change is defined as a change which does not cause any change in chemical composition of a substance.
For example, change in shape, size, mass, volume etc are all characteristics of physical change.
Whereas a change that causes change in chemical composition of a substance is known as chemical change.
For example,

A new substance is always formed in a chemical change.
Thus, we can conclude that the definition a chemical change produces a new substance by breaking and forming new bonds, is correct.