Answer: The 234.74 grams of sample should be ordered.
Step-by-step explanation:
Let the gram of 114 Ag to ordered be
![N_o](https://img.qammunity.org/2020/formulas/chemistry/high-school/vtrywdc4yefdxl0zw3d7sugtn6ogov7dmq.png)
The amount required for the beginning of experiment = 0.0575 g
Time requires to ship the sample = 4.2hour = 252 min(1 hr = 60 min)
Half life of the sample =
= 21 min
![\lambda =\frac{0.693}{t_{(1)/(2)}}=(0.693)/(21 min)=0.033 min^(-1)](https://img.qammunity.org/2020/formulas/chemistry/high-school/24v9wzh2d4l40enwnfwihwi6uosbny48hd.png)
![\log[N]=\log[N_o]-(\lambda t)/(2.303)](https://img.qammunity.org/2020/formulas/chemistry/high-school/o2xfx99aycbbozxd1odqqt5swf89xb8jm4.png)
![\log[0.0575 g]=\log[N_o]-(0.033 min^(-1)* 252 min)/(2.303)](https://img.qammunity.org/2020/formulas/chemistry/high-school/705s4zr38abjm45iet956p7ol5dy8d2e6u.png)
![N_o=234.74 grams](https://img.qammunity.org/2020/formulas/chemistry/high-school/4i7516ihke13m48it79rfpei53mewk8y5f.png)
The 234.74 grams of sample should be ordered.