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The liquids having same boiling point cannot be seperated from its mixture by distillation, why?​

User Jin Kwon
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2 Answers

15 votes
15 votes

Answer:

Step-by-step explanation:

They cannot be separated by distillation since it depends on a liquid's ability to boil at a certain temperature. If you have two liquids with the same boiling temperatures, the proportion of each in the vapor phase will be about equal, making it impossible to separate them. Although they presumably do not have the same freezing point, you might use a different method like chromatography or work with their freezing points instead. You could then selectively crystallize one component while leaving the other as a pure liquid.

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Definitions:

Distillation:

#1: The volatilization or evaporation and subsequent condensation of a liquid, as when water is boiled in a retort and then the steam is condensed in a cool receiver.

User Amador
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19 votes
19 votes

Answer:

Because different compounds often have different boiling points, the components often separate from a mixture when the mixture is distilled. The boiling point is the temperature at which the vapor pressure of the liquid phase of a compound equals the external pressure acting on the surface of the liquid.

Step-by-step explanation:

User Fender
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