Take east to be the positive direction. Then the resultant force from adding F₁ and F₂ is
F₁ + F₂ = (-45 N) + 63 N = 18 N
which is positive, so it's directed east.
To this we add a third force F₃ such that the resultant is 12 N pointing west, making it negative, so that
18 N + F₃ = -12 N
F₃ = -30 N
So F₃ has a magnitude of 30 N and points west.