Question

Carbohydrates like glucose can undergo spontaneous rearrangement to give an alternate configuration for the anomeric carbon when the ring is free in solution. However, when glucose is covalently attached to another sugar through C1, this rearrangement cannot occur. Consequently, the configuration of carbohydrate oligomers and polymers is fixed. Why can't glucose rearrange when in a polymer form?

Answer 1

The presentation according to another circumstance is categorized in the following section.

Step-by-step explanation:

Glucose constructs anomers because of the extreme involvement of flexible metal-carbon because that continues to exist as something of a monomer. However, when plastics are established, transformation is limited with glycoside formation of complexes among both anomeric carbon atoms.

• Sucrose, besides obvious reasons, would be manufactured by glucose and fructose, which have been connected by something like a glycerol backbone involving glucose carbon atom as well as fructose.
• The mechanism including its creation of anomers even by movement through carbon becomes called "Mutarotation" Sucrose doesn't always show mutation.