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The hybrid orbital set used by the central atom in no3- is_____ and why?

a. sp
b. sp3
c. SP2
d. sp3d2
e. sp3d

1 Answer

2 votes

Answer:

c. SP2

Step-by-step explanation:

The image in the diagram below shows the structure of NO₃⁻

Nitrogen is the central atom with the electronic configuration of 1s² 2s² 2p³.

So in its outermost shell, it has 3 electrons and the hybridization is sp²

However,

According to Hund's rule:

The ground state of Nitrogen is;

1s² 2s² 2p³

↑↓ ↑ ↑ ↑ ↑

At the excited state when it is attached to 3 different oxygen ions, we have:

1s² 2s² 2p⁵

O⁻ ---> ↑↓ ↑↓ ↑↓ ↑↓ ↑

1s² 2s² 2p⁵

O⁻ ---> ↑↓ ↑↓ ↑↓ ↑↓ ↑

1s² 2s² 2p⁴

O⁻ ---> ↑↓ ↑↓ ↑↓ ↑ ↑

Thus, the 3 sp² orbital lies in a plane and form 3 N - O σ- bond and one π- bond.

The hybrid orbital set used by the central atom in no3- is_____ and why? a. sp b. sp-example-1
User Robert Nishihara
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