There are multiple orbitals within an atom. Each has its own specific energy level and properties. Because each orbital is different, they are assigned specific quantum numbers: 1s, 2s, 2p 3s, 3p,4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f, 6d, 7p. The numbers, (n=1,2,3, etc.) are called principal quantum numbers and can only be positive numbers. The letters (s,p,d,f) represent the orbital angular momentum quantum number (ℓ) and the orbital angular momentum quantum number may be 0 or a positive number, but can never be greater than n-1. Each letter is paired with a specific ℓ value:
Ithink b.4f