If θ is the angle between u and v, then
u • v = ||u|| ||v|| cos(θ)
Since u = -3v, we have
u • v = (-3v) • v = -3 ||v||²
and
||u|| = ||-3v|| = 3 ||v||
If v₁ and v₂ are both not zero, then ||v| ≠ 0.
Then
cos(θ) = (-3 ||v||²) / (3 ||v|| ||v||) = 1
which means θ = π rad = 180°.