Final answer:
The biochemical standard state and the chemical standard state are used to define the standard state in free energy change calculations. The biochemical standard state is modified to fit biochemistry applications. Standard free energy change in biological systems typically occurs at pH 7.0, 25 degrees Celsius, and 1 atm pressure.
Step-by-step explanation:
The biochemical standard state and the chemical standard state are both used to define the standard state in free energy change calculations, but there are some differences between the two. The biochemical standard state is modified from the chemical standard state to fit biochemical applications. For example, in biochemistry, pH = 7 is commonly employed as the standard pH instead of a pH of zero. The standard free energy change of a chemical reaction is expressed either in kilojoules per mole (kJ/mol) or kilocalories per mole (kcal/mol) under standard pH, temperature, and pressure conditions. In biological systems, standard conditions are typically pH 7.0, 25 degrees Celsius, and 1 atm pressure.