Question

Write the limiting forms (or Canonical forms) of the following ions:

i. H3O+

, ii. CO3

2-

, iii. NO3-​

Answer 1

Canonical structures of a chemical specie explain its observed properties from a valence bond theory perspective.

Step-by-step explanation:

Resonance is a valence bond concept introduced by Linus Pauling to explain the observed properties of certain chemical species such as bond lengths, bond angles, bond order , etc.

There are certain chemical species for which a single chemical structure does not suffice in explaining its observed properties. For instance, the bond order in CO3^2- is about 1.33. Its bond length, shows that the C-O bond present in CO3^2- is neither a pure C-O single bond nor a pure C-O double bond. Hence the structure of CO3^2- is 'somewhere in between' three contributing canonical structures as shown in the image attached to this answer. The resonance structures of NO3^- are also shown.