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Citric acid, also known as vitamin C, is a triprotic acid with the formula H3C6H5O7. The pKa values are 3.13, 4.76, and 6.40. What will be the approximate pH of a solution of sodium monohydrogencitrate, Na2HC6H5O7?

User AaronJ
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1 Answer

3 votes

Answer:

pH = 5.58

Step-by-step explanation:

Given that :

Citric acid is a triprotic acid with the formula
H_3C_6H_5O_7 . Tripotic acids are acids that have the tendency to yield three protons per molecule during the phases of dissociation, therefore they have three pka.

For Citric acid; the pka values are:


pKa _1 = 3.13\\pKa_2 = 4.76\\pKa_3 = 6.40

So, the pH of sodiummonohydrogencitrate with the chemical formula
Na_2HC_6H_5O_7 which can act as an acid and a base (i.e it is said to be amphoteric) can be calculated as :


pH = (pKa_2+pKa_3)/(2)


pH = (4.76+6.40)/(2)

pH = 5.58

Therefore, the approximate pH of a solution of sodium monohydrogencitrate = 5.58

User Dancl
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