Answer : The original activity will be, 303 millicuries.
Explanation :
Half-life = 15 hr
First we have to calculate the rate constant, we use the formula :
![k=(0.693)/(t_(1/2))](https://img.qammunity.org/2021/formulas/physics/high-school/r5hcjtfgeqjn494d5382jkg40k18lzyfu3.png)
![k=(0.693)/(15hr)](https://img.qammunity.org/2021/formulas/physics/high-school/uz3rwlrm0nld5oq2zva9wlzru741ciyo31.png)
![k=4.62* 10^(-2)\text{ hr}^(-1)](https://img.qammunity.org/2021/formulas/physics/high-school/4lz2j2l0hdosad6lfdvljo92qo6b60mcbs.png)
Now we have to calculate the time passed.
Expression for rate law for first order kinetics is given by:
![t=(2.303)/(k)\log(a)/(a-x)](https://img.qammunity.org/2021/formulas/physics/high-school/34336uhzgbxxst4voy5o2jexos3nnuq6xo.png)
where,
k = rate constant =
![4.62* 10^(-2)\text{ hr}^(-1)](https://img.qammunity.org/2021/formulas/physics/high-school/xxm57rx1e2j3uvy8689xxc3168s0xoiews.png)
t = time passed by the sample = 24 hr
a = initial amount of the reactant = ?
a - x = amount left after decay process = 100 millicuries
Now put all the given values in above equation, we get
![24=(2.303)/(4.62* 10^(-2))\log(a)/(100)](https://img.qammunity.org/2021/formulas/physics/high-school/p07ydv0kktmsmg8pvr7da0htc7vp9fxtbt.png)
![a=302.97\text{ millicuries}\approx 303\text{ millicuries}](https://img.qammunity.org/2021/formulas/physics/high-school/znzwnwpczbyj5l32u86xuv36zrso69ao6n.png)
Therefore, the original activity will be, 303 millicuries.