Answer:
Hydrocyanic acid, HCN.
Step-by-step explanation:
A buffer is defined as the aqueous mixture of a weak acid and its conjugate base. Or a weak base and its conjugate acid. In the problem, we have a solution of potassium cyanide. The conjugate acid of potassium cyanide is hydrocyanic acid. A weak acid with pKa = 9.89.
That means, to convert the solution into a buffer we must add:
Hydrocyanic acid, HCN.