So, litmus paper is a qualitative tool for assessing the acidity or basicity of a substance (usually a solution). In general, blue litmus turns red in the presence of an acid, and red litmus turns blue in the presence of a base. They can't really tell you much more than that.
The solutions that are most likely acids are those that turn blue litmus red and do not evoke a color change in red litmus. A solution that turns red litmus blue or does not evoke a color change in blue litmus is likely not an acid. Using these criteria, solutions 4 and 7 are most likely acids since they both turn blue litmus red (and they cause no color change in red litmus).
The correct answer choice would thus be D.