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During a titration, the pH of an analyte solution containing HA(aq) is 3.92 and the ratio of [A–]/[HA] is 0.41. What is the Ka of HA?

User Testuser
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1 Answer

18 votes
18 votes

Answer:


Ka=4.71x10^(-4)

Step-by-step explanation:

Hello there!

In this case, according to the Henderson-Hasselbach equation, it is possible to write:


pH=pKa+log(([A^-])/([HA]) )

Next, since we are given the pH and the [A–]/[HA] ratio, we can solve for the pKa as shown below:


pKa=pH-log(([A^-])/([HA]) )

Now, we plug in the values to obtain:


pKa=3.92-log(0.41 )\\\\pKa=3.33

Next, Ka is:


Ka=10^(-pKa)=10^(-3.33)\\\\Ka=4.71x10^(-4)

Best regards!

User Heug
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