The gravitational potential enegy associated with the climber is 5.22x10⁶ J.
Given data:
The mass of mountain climber is m=85 kg.
The summit of volcano is h=6267 m.
The expression for the gravitaional potential energy is given by,

Here, g is the gravitational acceleration whose values is 9.81 m/s².
Substitute the given values in above expression,

Thus, the gravitational potential enegy associated with the climber is 5.22x10⁶ J.