When the object is in a circular motion, the direction of the velocity will be changing at every point on the path of the object. The object is pulled towards the center continuously.
The change in the velocity indicates that there is an acceleration acting on the object. This acceleration is directed radially inwards. And the velocity of the object, at any instant, is along the tangent to the circular path.
Hence the velocity vector and the acceleration vector are perpendicular to each other.
Thus, the correct answer is option a.