First, let's draw the vectors and the resultant vector:
In order to calculate angle theta, first let's find the angle created between the Force 1 in black and the Force 2 in purple. Then, angle theta will be supplementary to this angle, since the figure created is a parallelogram.
To find the angle above, we can use the law of cosines in the bottom triangle:
Now, let's calculate angle theta:
Rounding to one decimal place, we have theta equal to 66.3°.