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26 votes
8. A saturated solution of Ag Croq has a silver-ion concentration of 1.3 x 10-4M. Which is the Ksp of Ag CrO 4?

O 1.3 x 10-4
O 3.9 x 10-12
O 6.5 x 10-5
O 1.1 x 10-12

User Shadonar
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1 Answer

19 votes
19 votes

Answer: The
K_(sp) of
AgCrO_(4) is
1.1 * 10^(-12).

Step-by-step explanation:

Given:
[Ag^(+)] = 1.3 * 10^(-4) M

The reaction equation will be written as follows.


Ag_(2)CrO_(4) \rightleftharpoons 2Ag^(+) + CrO^(2-)_(4)

This shows that the concentration of
CrO^(2-)_(4) is half the concentration of
Ag^(+) ion. So,


[CrO^(2-)_(4)] = (1.3 * 10^(-4))/(2)\\= 0.65 * 10^(-4) M

The expression for
K_(sp) of this reaction is as follows.


K_(sp) = [Ag^(+)]^(2)[CrO^(2-)_(4)]

Substitute values into the above expression as follows.


K_(sp) = [Ag^(+)]^(2)[CrO^(2-)_(4)]\\= (1.3 * 10^(-4))^(2) * 0.65 * 10^(-4)\\= 1.1 * 10^(-12)

Thus, we can conclude that the
K_(sp) of
AgCrO_(4) is
1.1 * 10^(-12).

User Mitchken
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