Charge is "quantized". This means that charge comes in little pellets of a fixed amount. We can only get charge in whole pellets ... we can never cut up a pellet and get only a part of it.
The amount of charge in one pellet is 1.602 x 10⁻¹⁹ C.
That's the amount of negative charge on one electron, and it's also the amount of positive charge on one proton. Every electric charge in Creation must be a multiple of this amount.
a. -2.4*10-18 C
Yes. This charge can exist in Nature. It's the charge on 15 electrons.
b. 6.2*10-18 C
No. This charge can't exist in Nature.
38 protons carry 6.09 x 10⁻¹⁸ C (too small), but 39 protons carry 6.25 x 10⁻¹⁸ C (too big).