Answer:
5/36
Explanation:
We can model the possible outcomes for rolling a 6-sided die twice in a table:

These are only a third of the possible outcomes. However, analyzing the sum columns, we can extrapolate the rest of the outcomes:
sum1 sum2 sum3 sum4 sum5 sum6
2 3 4 5 6 7
3 4 5 6 7 8
4 5 6 7 8 9
5 6 7 8 9 10
6 7 8 9 10 11
7 8 9 10 11 12
The number in "sum#" represents the second roll, and the row number (starting from 1 at the top) represents the first roll.
We can see that there are 5 possible outcomes where 6 is the sum of the rolled numbers, so P(sum of 6) = 5/36.