Answer: To solve this problem, you can use the first-order rate equation, which is given by:
[reactant] = [reactant]0 * e^(-k*t)
where [reactant] is the concentration of the reactant at time t, [reactant]0 is the initial concentration of the reactant, k is the rate constant, and t is the time.
Plugging in the given values, we get:
[reactant] = 1.304 M * e^(-4.10 x 10^-3 M s^-1 * 90.45 s)
= 1.304 M * e^(-0.0366)
= 1.304 M * 0.933
= 1.21 M
To express the answer with 3 significant figures, you can round the answer to 1.21 M. Therefore, the concentration of the reactant after 90.45 seconds is 0.933 ± 1%.