A) Relative frequency is number of times an event happened over total number of events:
Answer is 21/50 = 0.42
B) On a 6 sides die, there are 3 even numbers and 3 odd numbers, so the theoretical probability of landing on odd would be 3/6 = 0.50
C) Because the die has an equal amount of chance landing on even or odd, both are 3/6, then the dice is not biased.