Final answer:
Beyond the equivalence point of a titration with acetic acid and NaOH, the major species in the solution include sodium ions (Na+) as spectator ions, excess hydroxide ions (OH-), and acetate ions (Ac-).
Step-by-step explanation:
At the end point of a titration between acetic acid (HAc) and sodium hydroxide (NaOH), the acetic acid has been neutralized, forming water (H2O) and the acetate ion (Ac-).
Beyond the equivalence point, the major species present in the reaction flask would therefore be the sodium ions (Na+) as spectator ions, excess hydroxide ions (OH-) from the NaOH, and acetate ions (Ac-) from the neutralized acetic acid.
The sodium ions do not participate in the reaction and are thus considered spectator ions; they can be removed when writing the net ionic equation.
After the equivalence point, the pH of the solution is determined by the concentration of these hydroxide ions.