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A student completes a titration of 30 ml of an unknown NaOH solution with HCl. What is the molarity of the NaOH solution if 25 ml of HCl is required to neutralize it?

A) 0.75 M
B) 1.20 M
C) 1.50 M
D) 2.40 M

1 Answer

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Final answer:

The molarity of the NaOH solution is determined to be 1.20 M by using the stoichiometry of the titration reaction and the volumes of HCl and NaOH involved, where the reaction has a 1:1 molar ratio between HCl and NaOH.

Step-by-step explanation:

To determine the molarity of NaOH solution, we will use the concept of titration and the stoichiometry of the reaction. Sodium hydroxide (NaOH) and hydrochloric acid (HCl) react in a 1:1 molar ratio, as shown in the balanced equation:

NaOH(aq) + HCl(aq) → NaCl(aq) + H₂O(l)

The molarity of NaOH can be calculated using the volume and molarity of HCl that was required to neutralize it. As the balanced equation shows a 1:1 stoichiometry, the moles of NaOH will be equal to the moles of HCl used.

To find the moles of HCl:
# moles HCl = Volume HCl (L) × Molarity HCl (M)
# moles HCl = 0.025 L × M

Since the volume of HCl is given as 25 mL, we need to convert this to liters (L) by dividing by 1000 mL/L (25 mL ÷ 1000 mL/L = 0.025 L). Now we can calculate the moles of NaOH which will be the same as the moles of HCl since they react 1:1:

# moles NaOH = # moles HCl = 0.025 L × M

To find the molarity of the NaOH solution, use the formula:
Molarity NaOH = moles NaOH / Volume NaOH (L)

We have the volume of NaOH solution as 30 mL, which is 0.030 L. Using the equation:

Molarity NaOH = (0.025 L × M) / 0.030 L

By solving for M, we find that the molarity of NaOH is 1.20 M, which corresponds to answer choice (B).

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