Final answer:
The true statement for a 0.10 M solution of HCl is [H₃O⁺] = 0.10 M, as HCl is a strong acid and fully dissociates in solution. a.[H₃O⁺]ₑᵩ = 0.10 M
Step-by-step explanation:
The question asks which statement is true for a 0.10 M solution of HCl concerning the concentration of hydronium ions, [H₃O⁺]. Since hydrochloric acid (HCl) is a strong acid, it dissociates completely in water, meaning that the concentration of HCl before dissociation will be equal to the concentration of hydronium ions after dissociation.
Therefore, for a 0.10 M solution of HCl, the concentration of hydronium ions, [H₃O⁺], will also be 0.10 M. Thus, the correct statement is [H₃O⁺] = 0.10 M. The application of the formula pH = -log[H₃O⁺] confirms this since the calculated pH of a 0.10 M HCl solution is exactly 1, which reflects the corresponding hydronium ion concentration.
To maintain the equilibrium where the product of the concentrations of hydronium ions and hydroxide ions is always 1.0×10⁻¹⁴ at 25 °C, the concentration of hydroxide ions will be appropriately lower in the acidic solution of HCl.