Final answer:
To prove △ABC≅△DEF by the ASA postulate, Angle A must be congruent to Angle D, Angle B must be congruent to Angle E, and Side AC must be congruent to Side DF.
Step-by-step explanation:
In order to show that △ABC≅△DEF by the ASA (Angle-Side-Angle) postulate, we need to prove that two angles and the included side of one triangle are congruent to the corresponding angles and included side of the other triangle.
So, to prove △ABC≅△DEF, we need to prove that Angle A is congruent to Angle D, Angle B is congruent to Angle E, and Side AC is congruent to Side DF.