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Is there nice way to see/show/derive why p orbitals are so important for stability? Or asked differently: Why are elements with filled p orbitals on the right side of the periodic table? Why aren't elements with fully filled s or d shell like Beryllium or Zinc noble?

User Gooziec
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Final answer:

P orbitals contribute to stability due to their role in achieving a filled valence shell, leading to a noble gas configuration, which is the most stable arrangement. Elements with fully filled p orbitals, such as noble gases, are inert and do not readily form chemical bonds, unlike elements with filled s or d orbitals.

Step-by-step explanation:

The importance of p orbitals for stability can be understood by looking at the periodic table and electron configurations. The noble gases found on the right side of the periodic table (Group 18) have filled p orbitals in their outermost energy level, which leads to a stable, noble gas configuration. Unlike p orbitals, when s orbitals are filled, such as in Beryllium, or d orbitals, like in Zinc, the electron configuration is stable but not to the same extent as a filled p orbital, which represents a completed energy level and the maximum stability within its period.

Elements with a filled outermost p orbital, such as helium (He), neon (Ne), and argon (Ar) are nonreactive and are labeled inert or noble gases. In contrast, elements to the left of the periodic table, like hydrogen (H), lithium (Li), and sodium (Na), tend to lose an electron to attain stability. Transition elements like copper (Cu) and chromium (Cr) show, via their electron configurations, that elements can sometimes rearrange electrons to achieve half-filled or fully filled d orbitals, which are more stable configurations than having those electrons in the s orbital.

Through quantum mechanics and the concept of electron orbitals, we understand that electrons behave not just like particles but also like waves, and exist in orbitals that are not simply circles around the nucleus but have complex shapes. Valence electrons, particularly those in p orbitals, play a significant role in chemical reactions and as such, can explain why elements with filled p orbitals are particularly stable.

User Blyabtroi
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