Final answer:
Option D is answer, a process known as Batesian mimicry where harmless species mimic harmful ones to evade predators.
Step-by-step explanation:
The best statement that aligns with the evolutionary process for the adaptation of caterpillars resembling snakes when threatened is D) Mutations and natural selection contributing to the development of snake-like appearances as a defense mechanism. The evolution of such mimicry traits, such as those seen in caterpillars that display snake-like features when threatened, is an example of Batesian mimicry, which involves a harmless species evolving to imitate the features of a harmful or inedible species to evade predators.
This adaptive trait arises from random mutations generating variance among individuals, with natural selection favoring those whose appearance allows them to better avoid predation. This process is not immediate but occurs over many generations, as individuals with advantageous traits tend to survive and reproduce, passing those traits to their offspring.