Answer:
d) Air prevents excessive pressure buildup.
Step-by-step explanation:
When a glass bottle filled with vinegar is heated, both the vinegar and the glass expand. However, as you mentioned, vinegar expands more significantly with temperature than glass. This difference in expansion rates can lead to an increase in pressure inside the sealed bottle. If the bottle is tightly capped, the pressure can build up to a point where it exceeds the strength of the glass, causing it to break.
The pocket of air above the vinegar serves as a buffer. Air can compress and expand more easily than liquids or solids, so as the temperature increases and the vinegar expands, the air pocket can absorb some of this expansion, preventing excessive pressure buildup. This helps to avoid the glass breaking due to the increased internal pressure. It acts as a safety valve, allowing the system to equalize pressure without causing damage to the container.