Final answer:
The mixture of MgCl2 and KOH will produce a precipitate since Mg(OH)2 is insoluble, making this the correct answer. The correct answer is option d.
Step-by-step explanation:
To determine which pair of aqueous solutions will form a precipitate when mixed, we must consider the solubility rules and perform a double displacement reaction for each pair.
- HI + KOH: H2O and KI are formed, both of which are soluble.
- K2S + HBr: H2S and KBr are formed, but H2S is a gas, so no precipitate is formed.
- K2CO3 + HNO3: H2CO3 and KNO3 are formed, but H2CO3 decomposes to CO2 and H2O, so no precipitate is formed.
- MgCl2 + KOH: Here, Mg(OH)2 is formed, which is insoluble and will form a precipitate.
Given these reactions, the correct option is that the mixture of MgCl2 + KOH will produce a precipitate. So the correct answer is MgCl2 + KOH.