Final answer:
The experiment with the closest to stoichiometric quantities is experiment 4, which involved 1 mole of NaHCO3 and 1 mole of HC2H3O2, perfectly reflecting the 1:1 stoichiometric ratio required by the balanced chemical equation for their reaction.
Step-by-step explanation:
When comparing reaction experiments to find the one with the closest to stoichiometric quantities, we need to refer to the balanced chemical equation of the reaction between sodium bicarbonate (NaHCO3) and acetic acid (HC2H3O2). The balanced chemical equation is as follows:
NaHCO3 + HC2H3O2 → NaC2H3O2 + H2O + CO2
This indicates a 1:1 molar ratio between NaHCO3 and HC2H3O2. Therefore, the experiment with stoichiometric quantities would be the one that also reflects a 1:1 molar ratio.
Option d, which states one mole of NaHCO3 was present with one mole of HC2H3O2, matches this stoichiometic ratio and thus would be the experiment closest to stoichiometric quantities.
Option d, Experiment 4; 1 mole of NaHCO3 and 1 mole of HC2H3O2