The volume of the 6.25 L gas sample at STP is approximately 14.5 L, which is closest to 14.3 L. Here option C is correct.
The question is about calculating the new volume of a gas when changing conditions to Standard Temperature and Pressure (STP). To solve this, we use the combined gas law, where the pressure, volume, and temperature of a gas have the following relationship:

We know the initial conditions (
) and the final conditions at STP (
= 1 atm,
= 273 K). Using the given initial conditions:
= 6.25 L
= 298 K
We can plug these values into the combined gas law equation and solve for the final volume (
):

= (2.50 atm * 6.25 L * 273 K) / (298 K * 1 atm)
= (4312.5 L*K) / (298 K)
≈ 14.5 L
Therefore, the correct answer is near to Option C - 14.3 L, which is the volume of the gas at STP.