Final answer:
The correct choice is A) C6H14 and C10H20, as they are both nonpolar hydrocarbons and will likely form a homogeneous solution.
Step-by-step explanation:
To choose the pair of substances that are most likely to form a homogeneous solution, we look at the solubility rules and likeness in chemical structure or polarity. Among the given choices:
- A) C₆H₁₄ (hexane) and C₁₀H₂₀ (decane) are both nonpolar hydrocarbons and will likely form a homogeneous solution due to similar intermolecular forces.
- B) KCl (potassium chloride) is an ionic compound, while C5H₁₂ (pentane) is a nonpolar hydrocarbon. Their differing polarities make them unlikely to form a homogeneous solution.
- C) N₂O₄ (dinitrogen tetroxide) and NH₄I (ammonium iodide) are also unlikely to form a homogeneous solution due to the ionic nature of NH₄I and the molecular nature of N₂O₄.
- D) C₆H₁₄ (hexane) and H₂O (water) are immiscible due to hexane being nonpolar and water being polar.
- E) None of the pairs above will form a homogeneous solution. This is incorrect because C₆H₁₄ and C₁₀H₂₀ can form a homogeneous solution.
Therefore, the correct answer is A) C₆H₁₄ and C₁₀H₂₀.